Antoine Equation:
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The Antoine equation is a class of semi-empirical correlations that describes the relation between vapor pressure and temperature for pure substances. It's widely used in chemical engineering and thermodynamics to estimate vapor pressures.
The calculator uses the Antoine equation:
Where:
Explanation: The equation provides an accurate estimation of vapor pressure over a limited temperature range for many substances.
Details: Accurate saturation pressure estimation is crucial for designing distillation columns, predicting phase behavior, and understanding evaporation processes in various industrial applications.
Tips: Enter temperature in °C and the appropriate Antoine constants for your substance. The default values are for water. Ensure temperature is within the valid range for your substance's constants.
Q1: What are typical Antoine constants for water?
A: For water between 1-100°C, common values are A=23.1964, B=3816.44, C=-46.13 (with P in Pa and T in °C).
Q2: How accurate is the Antoine equation?
A: The Antoine equation is typically accurate to within 1-5% for most substances within their specified temperature ranges.
Q3: Can I use this for any substance?
A: Yes, but you need the appropriate Antoine constants for that specific substance, as they vary significantly between compounds.
Q4: What are the limitations of the Antoine equation?
A: It's only accurate within a limited temperature range and may not work well near the critical point or for complex mixtures.
Q5: How do I find Antoine constants for other substances?
A: Antoine constants are available in chemical engineering handbooks, thermodynamic databases, and specialized literature for many pure substances.